Okay so i bought this cake pop silicone mould.... so i baked red velvets in it and the cake pops didnt want to come out round... so i put more baking powder when i did that it came out round but it cracked... what do i do?????????????

AYou make them the traditional way. Very few people have had any success with molds/pans. I'm curious as to your reasoning for adding more leavening, rather than just adding more batter to the mold.